Fluid Power Journal

Alternatives to Mineral-Based Hydraulic Fluids in Steel Production

Manage Your Fire Risk Without Jeopardizing Your Productivity

By Ronald Knecht, Global Business Development Manager Fluid Power, Quaker Chemical Corp.

Steel production is an industry where situations occur every day that can be classified as dangerous. With operations involving heavy equipment and liquid or red-hot steel, the danger of fire is ever present. And fire hazards are often exacerbated when mineral oil-based hydraulic fluids are used.

Fire Risks of Hydraulic Fluids

A fire results in the risk of personal injuries, as well as a likelihood of loss in both capital and production. These losses include not only damage to the building and equipment, but also encompass interruptions in production that can idle production lines for days, or even months.

One cause of fire in a steel production plant is the ignition of mineral oil hydraulic fluids. The highest risk of fire in a steel production plant is the operations where the processed materials reach temperatures +/-1652°F up to >2732°F (+/-900°C up to > 1500°C). In most of these processes, hydraulic units are used to operate the equipment, and in many cases, a mineral oil-based hydraulic fluid is used to fuel the hydraulic unit. While mineral oil has the definite advantage of a good cost-performance ratio, it is a distillate from crude oil and not always the safest choice due to its tendency to catch fire easily. Fortunately, there are alternatives available to manage this risk and reduce the chance of an ignition without jeopardizing the performance or productivity.

Types of Fire-Resistant Hydraulic Fluids

The standard hydraulic fluids used in steel production are mineral oil based. However, an alternative to mineral oil hydraulic fluids are fire-resistant hydraulic fluids, as described in Table 1 using the ISO 6743/4 classification.

For each fluid type, there are both pros and cons. Table 2 shows a comparison of the performance properties of several hydraulic fluid types. The properties shown are considered important by both maintenance managers, as well as purchasers.

Properties of Hydraulic Fluid Types

  • Mineral oil provides good hydraulic fluid performance attributes at a reasonable price, as shown in Table 2. However, because mineral oil is not biodegradable, it is not environmentally friendly. And mineral oil delivers a higher total cost of operation when the risk of fire and worker safety is factored in the cost of use.
  • Phosphate ester (HFD-R) fluids, an older fluid technology, are fire-resistant by chemistry. However, they are formulated with materials considered to be CMR (Carcinogenic, Mutagenic, Reprotoxic). The combustion fumes they produce are neurotoxic. While these phosphate ester-based products provide good pump lubrication, they can limit the service life of servo valves. HFD-R fluids can be 10-15 times more expensive than mineral oil and need to be carefully maintained, as these products form aggressive acids as they age. Today, they are used mainly in power generation, although they are at times found in steel plants, as well.
  • Water glycols (HFC) are widely used in steel plants, as well as other industries, representing approximately 50% of the total fire-resistant hydraulic fluids market. Because of their high water content, HFC fluids provide very good fire resistance. In price, it is comparable to mineral oil and less expensive than water-free hydraulic fluids. However, HFCs don’t measure up in performance attributes. Component service life generally is shorter, more fluid management is needed, and energy consumption is 10 to 20% higher compared to mineral oil or polyol ester-based fire-resistant hydraulic fluids. All issues drive up the total cost of operation (TCO).
  • Polyol ester-based fluids (HFD-U) are the best alternative to mineral oil. While they are more expensive than mineral oil (approximately 2 to 3 times more), they deliver a lower total cost when you consider the reduction in fire risk and improvement in worker safety. Also, with polyol ester-based fluids, manufacturers don’t sacrifice the fluid’s performance, and they are environmentally friendly.

Understanding the Term “Fire Resistant”

“Fire-resistant” is often misunderstood to be the same as “fire-retardant”—or the ability to suppress a flame. The only hydraulic fluids that can truly be considered fire-retardant are the high water content (HFA) fluids. Almost all fire-resistant hydraulic fluids will burn under certain conditions. HFC fluids will ignite if a certain amount of water evaporates. And while most HFD-U fluids will burn, they will not cause the ignition-like explosion that the mineral oil will, which leads to an uncontrollable situation.

Fluids can be tested to determine their fire resistance. The most common and generally accepted tests are those used by Factory Mutual (FM Global), the testing and approval arm of a major industrial insurance underwriter (www.fmglobal.com). By using an FM Global-approved hydraulic fluid, manufacturers can often reduce their insurance premium. Many other organizations and companies have also developed fire-resistance tests, usually to simulate a certain type of real-world accident.

Choose Change Over Experience

Polyol ester technology has been in use for about half a century and in many fire-hazardous applications in steel mills—from blast furnaces to hot strip mills. If a manufacturer makes the decision to change to a polyol ester fluid in their hydraulic system, the conversion process is not complicated. Typically, no changes need to be made to the hydraulic unit when converting from a mineral oil or water glycol hydraulic fluid to a polyol ester fluid. That said, the conversion must be done with care because there are several grades and qualities of polyol ester (HFD-U) fluids available on the market.

The important checks that must be performed are not only compatibility evaluations with the existing mineral oil, but also the paint inside the tank, seals, hoses, valves, and pump. In the end, tests will show that the type of paint is critical (single-component paints can be incompatible), as well as pump approvals. It is also important to remember that several different suppliers exist for polyol ester fluids, but most pump builders only approve some suppliers without any restriction on rpm and maximum pressure. Experience teaches that when paint compatibility is good, no changes or restrictions are needed for the hydraulic system. To guarantee the fire resistance of the new fluid, less than 5% residual mineral oil should remain.

Case studies of steel customers who switched to a fire-resistant hydraulic fluid after having experienced the hazards of mineral oil-based hydraulic fluids

1. A customer was operating a billet caster with a standard mineral oil-based hydraulic fluid. In this specific application, there were frequent hose ruptures that caused the oil to be splashed on the recently still-hot casted billets. Each time a rupture occurred, the fluid ignited into a massive fire with vapor clouds forming into fire balls. The fires were difficult to get under control, and each one caused hours of production lost due to downtime. After the customer switched to a fire-resistant hydraulic fluid, while the hose ruptures still took place (as it is induced by the surrounding environment), no more explosions of vapors took place and the situation was quickly under control.

2. In a customer’s operations, leaks were causing the mineral oil-based hydraulic fluid to form a pool on the plant floor. While the operation was running, liquid metal sparks would land in the oil pool and catch fire. The fire would spread quite rapidly, and although it caused no serious collateral damage, the potential threat was clearly demonstrated. Concerned with what could have potentially happened, the customer performed a test to compare hydraulic fluids for fire resistance. To do this, they placed a red-hot piece of steel into a bucket filled with mineral oil-based hydraulic fluid and another into a bucket filled with water-free, fire-resistant hydraulic fluid. The bucket containing mineral oil burned until it was empty (more than one hour). The bucket containing water-free, fire-resistant hydraulic fluid extinguished in less than 60 seconds. Seeing the results, the customer converted to fire-resistant hydraulic fluid.

3. Although seen as a relative cold area, many fires take place at the pickling line, specifically the hydraulic welder. Several accidents have been reported where hydraulic hoses ruptured and mineral oil-based hydraulic fluid came as a jet stream, landing on the just-generated weld or welding sparks, and set the whole area on fire. This not only caused severe damage in the surrounding area, but also idled the production line for several months. By switching to a fire-resistant hydraulic fluid, the risk of fire spreading to other areas of the plant was strongly reduced, as was long, costly downtime.

4. A steel customer was using mobile equipment to transport hot slag from its steel-making facility when an accident took place. The equipment’s mineral oil-based hydraulic fluid caught fire, and the mobile equipment was burned beyond repair. All the customer’s mobile units were immediately converted to a water-free, fire-resistant hydraulic fluid.

For more information, visit www.quakerchem.com or call 610-832-4000.

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